Bulk photovoltaic effect in batio3

Using the ferroelectric insulator BaTiO 3 we show how photogeneration and the collection of hot, non-equilibrium electrons through the bulk photovoltaic effect (BPVE) yields a greater-than-unity quantum efficiency.
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Anomalous photovoltaic effect

The anomalous photovoltaic effect (APE) is a type of a photovoltaic effect which occurs in certain semiconductors and insulators. The "anomalous" refers to those cases where the photovoltage (i.e., the open-circuit voltage caused by the light) is larger than the band gap of the corresponding semiconductor some cases, the voltage may reach thousands of volts.

Power conversion efficiency exceeding the Shockley–Queisser

Using the ferroelectric insulator BaTiO3 we show how photogeneration and the collection of hot, non-equilibrium electrons through the bulk photovoltaic effect (BPVE) yields a greater-than-unity

Shift current bulk photovoltaic effect in polar materials—hybrid

The bulk photovoltaic effect (BPVE) refers to the generation of a steady photocurrent and above-bandgap photovoltage in a single-phase homogeneous material lacking inversion symmetry. The

Does tetragonal ferroelectric Batio 3 induced surface photovoltage?

Here, taking a tetragonal ferroelectric BaTiO 3 single crystal as a prototype, we report an approach for distinguishing the shift and ballistic mechanism-induced surface photovoltage. The results indicate different effects on the charge separation of the ballistic mechanism and shift mechanisms, as evidenced by surface photovoltage measurement.

Bulk photovoltaic effect in ferroelectrics

The photovoltaic (PV) effect is a process by which materials or interfaces under light illumination generate voltages and electric currents. Because of the growing demand for sustainable energy supply and light communication, the importance of PV technologies is continuously increasing. 1) While semiconductor pn junctions are the most familiar devices

Power conversion efficiency exceeding the Shockley–Queisser

Using the ferroelectric insulator BaTiO 3 we show how photogeneration and the collection of hot, non-equilibrium electrons through the bulk photovoltaic effect (BPVE) yields a...

Anomalous circular bulk photovoltaic effect in BiFeO

The authors study the evolution of the bulk photovoltaic effect in BiFeO3 thin films with stripe-domains as the polarization of light is modulated from linear to circular. A relationship between

Anomalous photovoltage in BaTiO3

Abstract In ferroelectric melt-grown BaTiO3 single crystals steady-state short-circuit photocurrents have been observed parallel to the c-axis. At room temperature light polarized parallel and perpendicular to the c-axis produces short-circuit photocurrents with opposite sign. Along with the temperature dependence a physical model of this effect is outlined.

Ferroelectricity and Giant Bulk Photovoltaic Effect in BaTiO3

The conversion efficiency of the Bulk Photovoltaic Effect at the nanoscale could be extremely large. It is experimentally shown for heteroepitaxial BaTiO 3 films with thickness 20 and 40 nm. For nanoscaled BaTiO 3 films the conversion efficiency is 4,5 orders of magnitude larger as compared to the bulk crystals.

Strong bulk photovoltaic effect in engineered edge-embedded

The bulk photovoltaic effect (BPVE) is a nonlinear optical effect offering a promising approach to overcome the limitations of conventional photovoltaics. Here, the authors report the observation

Does ferroelectric Ba1 polarize better than BaTiO3?

In this work, ferroelectric Ba1- with improved polarization characteristics, and it is found to exhibits large PV response. Both compared to the parent BaTiO3. Short-circuit current measured as a function of light intensity and light polarization angle reveal linear and sinusoidal response, respectively. The observed

Bulk Photovoltage Effect in Ferroelectric BaTiO 3

Due to the unusual charge separation mechanism and anomalous photovoltaic effects, the bulk photovoltage effect in ferroelectric semiconductors has attracted a great deal of attention in solar energy conversion, especially in attempts to utilize nonthermalized carriers. Among the various mechanisms that have been proposed for interpreting the

Does the bulk photovoltaic effect increase quantum efficiency?

Using the ferroelectric insulator BaTiO 3 we show how photogeneration and the collection of hot, non-equilibrium electrons through the bulk photovoltaic effect (BPVE) yields a greater-than-unity quantum efficiency.

Ferroelectricity and Giant Bulk Photovoltaic Effect in BaTiO 3

The ferroelectric and photovoltaic properties of BaTiO3 films at the nanoscale are considered. The switching and scaling of the coercive field in the hetero epitaxial BaTiO3 films with thickness 3

Does ferroelectric Ba1 exhibit a large photovoltaic response?

The ferroelectric systems exhibiting anomalous photovoltaic effect are mostly crystallized with multiphase coexistence. Hence, the studies through phenomenological and shift current theory. In this work, ferroelectric Ba1- with improved polarization characteristics, and it is found to exhibits large PV response.

Flexo-photovoltaic effect in MoS2 | Nature Nanotechnology

Using strain-gradient engineering, the flexo-photovoltaic effect, that is, the strain-gradient-induced bulk photovoltaic effect, can be activated in centrosymmetric semiconductors, considerably

Enhancing ferroelectric photovoltaic effect of BaTiO3 by the

A large bandgap significantly suppress the development of ferroelectric photovoltaic (FE-PV). The bandgap of BaTiO 3 decreases to 1.49 eV from 2.46 eV by the formation of the lateral interface structure with BaO based on first principles calculations, which is beneficial to enhance the visible-light adsorption of FE-PV materials. The electronic structures

Bulk photovoltaic effect in BaTiO$_3$-based ferroelectric oxides:

In this work, ferroelectric Ba 1−x (Bi 0.5 K 0.5) x TiO 3 (BBKT) oxide is designed to crystallize in single-phase tetragonal symmetry with improved polarization characteristics, and

Linear bulk photovoltaic effect and phenomenological study

Research on the Influence of Photovoltaic Module Power Generation Efficiency and Manufacturing Technology on Power Grid Connection Qingyuan Fang-Reactive PowerControl of Grid-Connected Photovoltaic Power Generation LiJun Jin, XueJiao Gong, QiYa Sun et al.-Recent citations Bulk photovoltaic effect in BaTiO3-based ferroelectric oxides: An

Bulk photovoltaic effect in BaTiO3-based ferroelectric oxides:

response.2,7-11 Among them, the bulk photovoltaic effect (BPVE), associated with the violation of the detailed balance principle, is a widely accepted mechanism.2,6,10,11 The anomalous PV effects in several non-centrosymmetric systems having single and multiple phase co-existence such as BTO, PbTiO 3, BiFeO 3, KNbO 3, (K,Ba)(Ni,Nb)O 3-δ, ZnSnP 2

Enhancing ferroelectric photovoltaic effect of BaTiO3 by the

A large bandgap significantly suppress the development of ferroelectric photovoltaic (FE‐PV). The bandgap of BaTiO3 decreases to 1.49 eV from 2.46 eV by the formation of the lateral interface

Enhanced intrinsic photovoltaic effect in tungsten disulfide

A bulk photovoltaic effect is observed in devices based on tungsten disulfide, and is enhanced if the devices take the form of polar nanotubes, showing the importance of reducing crystal symmetry

Recent progress in the theory of bulk photovoltaic effect

The bulk photovoltaic effect (BPVE), sometimes also called the photogalvanic effect (PGE), refers to the electric current generation in a homogeneous material under light illumination, in contrast to the traditional photovoltaics where a heterojunction, such as a p–n junction, is needed to separate the photo-generated carriers (). 1–4 It has attracted increasing

Giant bulk photovoltaic effect in thin ferroelectric BaTiO 3 films

The voltage generated in a noncentrosymmetric crystal due to the bulk photovoltaic effect (BPE) can greatly exceed the energy gap, however, the light energy conversion efficiency is extremely low.

What is the bulk photovoltage effect in ferroelectric semiconductors?

NEXT Cite this: J. Phys. Chem. Lett. 2022, 13, 48, 11071–11075 Due to the unusual charge separation mechanism and anomalous photovoltaic effects, the bulk photovoltage effect in ferroelectric semiconductors has attracted a great deal of attention in solar energy conversion, especially in attempts to utilize nonthermalized carriers.

Hall-Bulk photovoltaic effect in BiFeO3/SrTiO3 at low

The bulk photovoltaic (BPV) effect, a nonlinear photo-response to the polarised light, can generate a directional photocurrent under uniform illumination in most non-centrosymmetric materials 1,2

Substantial bulk photovoltaic effect enhancement via nanolayering

Studies of photo-induced effects in ferroelectrics have experienced a revival due to the demonstration of a variety of fascinating physical effects, and in particular an increase in the power

S-doped BaTiO3 to regulate photovoltaic properties

Due to their unique ferroelectric photovoltaic (FEPV) effect, ferroelectric materials have attracted much attention in recent years for their potential application in solar cells [1, 2]. Ferroelectric materials exhibit spontaneous polarization, which may facilitate exciton separation and carrier extraction in bulk materials without the need for

About Bulk photovoltaic effect in batio3

About Bulk photovoltaic effect in batio3

Using the ferroelectric insulator BaTiO 3 we show how photogeneration and the collection of hot, non-equilibrium electrons through the bulk photovoltaic effect (BPVE) yields a greater-than-unity quantum efficiency.

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