Shift current photovoltaics


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Shift‐Current Photovoltaics Based on a Non‐Centrosymmetric

The shift-current photovoltaics of group-IV monochalcogenides has been predicted to be comparable to those of state-of-the-art Si-based solar cells. However, its exploration has

Shift current photovoltaic effect in a ferroelectric charge

Shift current is a steady-state photocurrent generated in non-centrosymmetric single crystals and has been considered to be one of the major origins of the bulk photovoltaic effect. The

Shift current bulk photovoltaic effect in polar materials hybrid

Shift current bulk photovoltaic effect in polar materials—hybrid and oxide perovskites and beyond Liang Z Tan 1, Fan Zheng, Steve M Young 2, Fenggong Wang 1, Shi Liu 3 and Andrew M Rappe 1

Shift Current photovoltaic e ect

Shift Current photovoltaic e ect Sean Raglow December 12, 2020 Abstract The bulk photovoltaic e ect (BPVE) is a nonlinear optical e ect that generates photocurrents in materials with broken inversion symmetry without the presence of an external dc electric eld. This e ect has garnered interest due to its potential applications in highly e cient

Design principles for shift current photovoltaics

While the basic principles of conventional solar cells are well understood, little attention has gone towards maximizing the efficiency of photovoltaic devices based on shift currents. By analysing effective models, here we outline simple design principles for the optimization of shift currents for

d arXiv:1507.08677v2 [cond-mat.mes-hall] 10 Aug 2015

Design principles for shift current photovoltaics Ashley M. Cook,1,2 Benjamin M. Fregoso, 1Fernando de Juan, and Joel E. Moore1,3 1Department of Physics, University of California, Berkeley, California, 94720, USA 2Department of Physics, University of Toronto, CAN 3Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720

Spectral dynamics of shift current in ferroelectric semiconductor

The ultrafast evolution of the shift current in a prototypical ferroelectric semiconductor antimony sulfur iodide (SbSI) is observed by detecting emitted terahertz electromagnetic waves. Significance Shift current is one of the bulk photovoltaic phenomena in the materials without inversion symmetry, originating from the geometric Berry phase of the

First-principles calculation of shift current bulk photovoltaic effect

Shift current is the dominant dc-current response in the bulk photovoltaic effect (BPVE), which is the conversion of solar energy into electricity in the materials with broken

First Principles Calculation of the Shift Current Photovoltaic

28 Using the shift current theory, we successfully predict short circuit photocurrent direction, 29 magnitude, and spectral features, demonstrating that shift current dominates the

Current-Voltage Characteristic and Shot Noise of Shift Current

We theoretically study the current-voltage relation, the I − V characteristic, of the photovoltaics due to the shift current, i.e., the photocurrent generated without the external dc electric field in noncentrosymmetric crystals through the Berry connection of the Bloch wave functions. We find that the I − V characteristic and shot noise are controlled by the difference

Shift Current Photovoltaics based on A Noncentrosymmetric

The shift current photovoltaics of group IV monochalcogenides have been predicted to be comparable to those of state-of-the-art Si-based solar cells. However, its exploration has been prevented from the centrosymmetric layer stacking in the thermodynamically stable bulk crystal. Herein, we stabilized the noncentrosymmetric layer stacking of tin

PHYSICAL REVIEW X 10, 041041 (2020)

photovoltaic effect by revealing the complete quantum geometric meaning of the second-order optical conductivity tensor. The bulk photovoltaic effect has two origins, which are the transition of electron called the shift current and the injection current. Based on an analysis of two-band models, we show that the injection current is

Shift current photovoltaic effect in a ferroelectric charge-transfer

Shift current is a steady-state photocurrent generated in non-centrosymmetric single crystals and has been considered to be one of the major origins of the bulk photovoltaic effect. The mechanism of this effect is the transfer of photogenerated charges by the shift of the wave functions, and its amplitude is closely related to the polarization

Shift current bulk photovoltaic effect in polar materials—hybrid

In this review article, we discuss the bulk photovoltaic effect (BPVE), in particular, the shift current mechanism, which has a number of advantages over traditional p–n junction

Design principles for shift current photovoltaics

Given these numbers, our work is a sign that shift current photovoltaics capable of surpassing conventional solar cells may be close at hand, and a push to investigate their full potential using methods discussed in this work—along with established techniques—is warranted. We believe that the simple principles derived in our work will serve

Current-Voltage Characteristic and Shot Noise of Shift

I V characteristics of shift current photovoltaics | In the experimental setup to measure shift current, an electrical circuit is formed by attaching two electrodes to the crystal and including resistors as shown in Fig. 1(a). The relationship between the voltage between the two electrodes and the current owing through the crystal is

Flexo-photovoltaic effect in MoS2 | Nature Nanotechnology

The shift current j sh is caused by the displacements of electrons in real space on quantum transitions M. et al. Shift current photovoltaic effect in a ferroelectric charge-transfer complex. Nat.

Shift-current bulk photovoltaic effect influenced by

Shift current bulk photovaltaic e ect in uenced by quasiparticle and exciton Ruixiang Fei,1 Liang Z. Tan,2 and Andrew M. Rappe1, 1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA 2Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States We compute the shift

Shift current photovoltaic efficiency of 2D materials | npj

Shift current photovoltaic devices are potential candidates for future cheap, sustainable, and efficient electricity generation. In the present work, we calculate the solar

Phys. Rev. B 101, 045104 (2020)

We compute the shift-current bulk photovoltaic effect (BPVE) in bulk ${mathrm{BaTiO}}_{3}$ and two-dimensional monochalcogenide SnSe considering quasiparticle corrections and exciton effects. We explore changes in shift-current peak position and magnitude reduction due to band renormalization. For BaTiO3, we demonstrate that shift current reduces

Design principles for shift current photovoltaics

This work uses a simple design principles approach to identify two classes of shift current photovoltaics, ferroelectric polymer films and single-layer orthorhombic monochalcogenides such as GeS, which display the largest band edge responsivities reported so far. While the basic principles of conventional solar cells are well understood, little attention has gone towards

Switchable magnetic bulk photovoltaic effect in the two

The bulk photovoltaic effect (BPVE) rectifies light into the dc current in a single-phase material and attracts the interest to design high-efficiency solar cells beyond the pn junction paradigm.

Shift‐Current Photovoltaics Based on a Non‐Centrosymmetric

The shift-current photovoltaics of group-IV monochalcogenides has been predicted to be comparable to those of state-of-the-art Si-based solar cells. However, its exploration has been prevented from the centrosymmetric layer stacking in the thermodynamically stable bulk crystal. Herein, the non-centrosymmetric layer stacking of tin sulfide (SnS

Are solar-generated shift current photovoltaic devices a viable energy source?

Shift current photovoltaic devices are potential candidates for future cheap, sustainable, and efficient electricity generation. In the present work, we calculate the solar-generated shift current and efficiencies in 326 different 2D materials obtained from the computational database C2DB.

Does shift photovoltaic current coexist with ballistic currents?

No eLetters have been published for this article yet. Science The quantum phenomenon of shift photovoltaic current was predicted decades ago, but this effect was never observed directly because shift and ballistic currents coexist. The atomic-scale relaxation...

Direct observation of shift and ballistic photovoltaic currents

Here, we report a facile, direct-current, steady-state method for unambiguous determination of shift by means of the simultaneous measurements of linear and circular bulk photovoltaic

Can shift currents improve photovoltaic efficiency?

Nature Communications 8, Article number: 14176 (2017) Cite this article While the basic principles of conventional solar cells are well understood, little attention has gone towards maximizing the efficiency of photovoltaic devices based on shift currents.

Is the shift mechanism responsible for photovoltaic current in a crystal?

In a number of recent experimental works (18 – 24), it has been reported that the shift mechanism may be responsible for any photovoltaic current in a crystal lacking inversion symmetry and may account for enhanced BPE (25, 26) and even anomalously large carrier collection length arising from local excitation (23, 24, 27).

First Principles Calculation of the Shift Current Photovoltaic Effect

We calculate the bulk photovoltaic response of the ferroelectrics BaTiO 3 and PbTiO 3 from first principles by applying the "shift current" theory to the electronic structure from density functional theory. The first principles results for BaTiO 3 reproduce experimental photocurrent direction and magnitude as a function of light frequency, as well as the

d arXiv:1507.08677v2 [cond-mat.mes-hall] 10 Aug 2015

identify two new classes of shift current photovoltaics, ferroelectric polymer lms and orthorhom- bic monochalcogenides, both of which exhibit peak photoresponsivities larger than predictions

Design principles for shift current photovoltaics

Design principles for shift current photovoltaics Ashley M. Cook1,2,*, Benjamin M. Fregoso1,*, Fernando de Juan1, Sinisa Coh1,w & Joel E. Moore1,3 While the basic principles of conventional solar cells are well understood, little attention has gone towards maximizing the efficiency of photovoltaic devices based on shift currents.

First Principles Calculation of the Shift Current Photovoltaic

of the bulk photovoltaic effect with shift current makes it clear that there is no direct, mechanistic dependence of response on material polarization, as is the case for many mechanisms to which photovoltaic effects in ferroelectrics have been attributed. However, shift current requires bro-

Introduction to the Shift Current Photovoltaic E ect

In this paper, I aim to describe the origins of the shift current photovoltaic e ect, and demonstrate the process for calculating its photoresponsivity for a simple tight binding model of the 2D

About Shift current photovoltaics

About Shift current photovoltaics

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